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RS危险和安全代码

RISK AND SAFETY STATEMENTS

(European Union Commission Directive 2001/59/EC defines hazard codes and phrases for classification, packaging and labeling of dangerous substances.For complete hazard and safety information always refer to the MSDS)

   

Risk Phrases

Indication of Particular Risks

R1: Explosive when dry
2: Risk of explosion by shock, friction, fire or other sources of ignition
3:   Extreme risk of explosion by shock, friction, fire or other sources of ignition
4:   Forms very sensitive explosive metallic compounds
5:   Heating may cause an explosion
6:   Explosive with or without contact with air
7:   May cause fire
8:   Contact with combustible material may cause fire
9:   Explosive when mixed with combustible material
10:   Flammable
11:  Highly Flammable
12:  Extremely Flammable
14:  Reacts violently with water
15:  Contact with water liberates extremely flammable gases
16:  Explosive when mixed with oxidizing substances
17:  Spontaneously flammable in air
18:  In use may form flammable/explosive vapor-air mixture
19:  May form explosive peroxides
20:  Harmful by inhalation
21:  Harmful in contact with skin
22:  Harmful if swallowed
23:  Toxic by inhalation
24:  Toxic in contact with skin
25:  Toxic if swallowed
26:  Very Toxic by inhalation
27:  Very Toxic in contact with skin
28:  Very Toxic if swallowed
29:  Contact with water liberates toxic gas
30:  Can become highly flammable in use
31:  Contact with acids liberates toxic gas
32:  Contact with acids liberates very toxic gas
33:  Danger of cumulative effects
34:  Causes burns
35:  Causes severe burns
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
39:  Danger of very serious irreversible effects
40:  Limited evidence of a carcinogenic effect
41:  Risk of serious damage to eyes
42:  May cause sensitization by inhalation
43:  May cause sensitization by skin contact
44:  Risk of explosion if heated under confinement
45:  May cause cancer
46:  May cause heritable genetic damage
48:  Danger of serious damage to health by prolonged exposure
49:  May cause cancer by inhalation
50:  Very Toxic to aquatic organisms
51:  Toxic to aquatic organisms
52:  Harmful to aquatic organisms
53:  May cause long-term adverse effects in the aquatic environment
54:  Toxic to flora
55:  Toxic to fauna
56:  Toxic to soil organisms
57:   Toxic to bees
58:   May cause long-term adverse effects in the environment
59:  Dangerous for the ozone layer
60:  May impair fertility
61:  May cause harm to the unborn child
62:  Possible risk of impaired fertility
63:  Possible risk of harm to the unborn child
64:  May cause harm to breast-fed babies
65:  Harmful: May cause lung damage if swallowed
66:  Repeated exposure may cause skin dryness or cracking
67:  Vapors may cause drowsiness and dizziness
68:  Possible risk of irreversible effects

 

  Combination of Particular Risks

 
R14/15:   Reacts violently with water, liberating extremely flammable gases
15/29:   Contact with water liberates toxic, extremely flammable gas
20/21:   Harmful by inhalation and in contact with skin
20/21/22:   Harmful by inhalation, in contact with skin and if swallowed
20/22:   Harmful by inhalation and if swallowed
21/22:   Harmful in contact with skin and if swallowed
23/24:   Toxic by inhalation and in contact with skin
23/24/25:   Toxic by inhalation, in contact with skin and if swallowed
23/25:   Toxic by inhalation and if swallowed
24/25:   Toxic in contact with skin and if swallowed
26/27:   Very Toxic by inhalation and in contact with skin
26/27/28:   Very Toxic by inhalation, in contact with skin and if swallowed
26/28:   Very Toxic by inhalation and if swallowed
27/28:   Very Toxic in contact with skin and if swallowed
36/37:   Irritating to eyes and respiratory system
36/37/38:   Irritating to eyes, respiratory system and skin
36/38:   Irritating to eyes and skin
37/38:   Irritating to respiratory system and skin
39/23:   Toxic: danger of very serious irreversible effects through inhalation
39/23/24:   Toxic: danger of very serious irreversible effects through inhalation in contact with skin
39/23/24/25:   Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
39/23/25:   Toxic: danger of very serious irreversible effects through inhalation and if swallowed
39/24:   Toxic: danger of very serious irreversible effects in contact with skin
39/24/25:   Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
39/25:   Toxic: danger of very serious irreversible effects if swallowed
39/26:   Very Toxic: danger of very serious irreversible effects through inhalation
39/26/27:   Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
39/26/27/28:   Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
39/26/28:   Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
39/27:   Very Toxic: danger of very serious irreversible effects in contact with skin
39/27/28:   Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
39/28:   Very Toxic: danger of very serious irreversible effects if swallowed
42/43:   May cause sensitization by inhalation and skin contact
48/20:   Harmful: danger of serious damage to health by prolonged exposure through inhalation
48/20/21:   Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
48/20/21/22:   Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed
48/20/22:   Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
48/21:   Harmful: danger of serious damage to health by prolonged exposure in contact with skin
48/21/22:   Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
48/22:   Harmful: danger of serious damage to health by prolonged exposure if swallowed
48/23:   Toxic: danger of serious damage to health by prolonged exposure through inhalation
48/23/24:   Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
48/23/24/25:   Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
48/23/25:   Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
48/24:   Toxic: danger of serious damage to health by prolonged exposure in contact with skin
48/24/25:   Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
48/25:   Toxic: danger of serious damage to health by prolonged exposure if swallowed
50/53:   Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
51/53:   Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
52/53:   Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
68/20:   Harmful: possible risk of irreversible effects through inhalation
68/20/21:   Harmful: possible risk of irreversible effects through inhalation and in contact with skin
68/20/21/22:   Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
68/20/22:   Harmful: possible risk of irreversible effects through inhalation and if swallowed
68/22:   Harmful: possible risk of irreversible effects if swallowed
68/21:   Harmful: possible risk of irreversible effects in contact with skin
68/21/22:   Harmful: possible risk of irreversible effects in contact with skin and if swallowed
68/22:   Harmful: possible risk of irreversible effects if swallowed

 

Safety Phrases

 

Indication of Safety Precautions

S1: Keep locked up
2: Keep out of the reach of children
3: Keep in a cool place
4: Keep away from living quarters
5: Keep contents under ... (appropriate liquid to be specified by the manufacturer)
6: Keep under ... (inert gas to be specified by the manufacturer)
7: Keep container tightly closed
8: Keep container dry
9: Keep container in a well-ventilated place
12: Do not keep the container sealed
13: Keep away from food, drink and animal feeding stuffs
14: Keep away from ... (incompatible materials to be indicated by the manufacturer)
15: Keep away from heat
16: Keep away from sources of ignition - No smoking
17: Keep away from combustible material
18: Handle and open container with care
20: When using, do not eat or drink
21:   When using, do not smoke
22: Do not breathe dust
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24: Avoid contact with skin
25: Avoid contact with eyes
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27: Take off immediately all contaminated clothing
28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
29: Do not empty into drains
30: Never add water to this product
33: Take precautionary measures against static discharges
35: This material and its container must be disposed of in a safe way
36: Wear suitable protective clothing
37: Wear suitable gloves
38: In case of insufficient ventilation, wear suitable respiratory equipment
39: Wear eye/face protection
40: To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
41: In case of fire and/or explosion do not breathe fumes
42: During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)
43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
46: If swallowed, seek medical advice immediately and show this container or label
47: Keep at temperature not exceeding ... E C (to be specified by the manufacturer)
48: Keep wetted with ... (appropriate material to be specified by the manufacturer)
49: Keep only in the original container
50: Do not mix with ... (to be specified by the manufacturer)
51: Use only in well-ventilated areas
52: Not recommended for interior use on large surface areas
53: Avoid exposure - obtain special instruction before use
56: Dispose of this material and its container to hazardous or special waste collection point
57: Use appropriate container to avoid environmental contamination
59: Refer to manufacturer/supplier for information on recovery/recycling
60: This material and/or its container must be disposed of as hazardous waste
61: Avoid release to the environment. Refer to special instructions safety data sheet
62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
63: In case of accident by inhalation, remove casualty to fresh air and keep at rest
64: If swallowed, rinse mouth with water (only if the person is conscious)
 

Combination of Safety Precautions

1/2:   Keep locked up and out of the reach of children
3/7:   Keep container tightly closed in a cool place
3/9/14:   Keep in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
3/9/14/49:   Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
3/9/49:   Keep only in the original container in a cool well-ventilated place
3/14:   Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
7/8:   Keep container tightly closed and dry
7/9:   Keep container tightly closed and in a well-ventilated place
7/47:   Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer)
20/21:   When using, do not eat, drink or smoke
24/25:   Avoid contact with skin and eyes
27/28:   After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer)
29/35:   Do not empty into drains, dispose of this container and it's material in a safe way
29/56:   Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point
36/37:   Wear suitable protective clothing and gloves
36/37/39:   Wear suitable protective clothing, gloves and eye/face protection
36/39:   Wear suitable protective clothing and eye/face protection
37/39:   Wear suitable gloves and eye/face protection
47/49:   Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer)


PICTOGRAMS AND HAZARD CODES

           

      

      

      

      

     

     

Explosive

Oxidizing

Extremely Flammable 
or Highly Flammable

Very Toxic or 
Toxic

Harmful or 
Irritant

Corrosive

Dangerous for 
the environment

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